Simple spectrophotometric determination of nonionic surfactants with a cationic azo dye
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چکیده
منابع مشابه
Aggregation of an anionic azo dye with conventional cationic surfactants in premicellar region: A conductometric study
The interaction of Congo Red CR with a series of Alkyltrimethylamoniumbromide CnTAB, N-hexadecylpyridinium bromide CPB and N-hexadecylpyridinium CPC were investigated using conductometry technique. It was observed that the formation of dye-surfactant ion pairs takes place at surfactant concentration far below the critical micelle concentration of the individual surfactants. Aggregation was refl...
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A simultaneous determination of cationic and nonionic surfactants has been developed using ion-association titration. Tetrabromophenolphthalein ethyl ester (TBPE) was used as an indicator. Benzalkonium reacted with TBPE to form a blue ion-associate in the organic phase. When tetrakis(4-fluorophenyl)borate was added dropwise to the solution, the color of the organic phase turned to yellow at the...
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A simple and direct spectrophotometric methods for determination of zinc are based on reaction with azo dyes: 1-(2-pyridylazo)-2-naphtol (PAN) and Chromothrop 2B in the presence benzyldimethyldodecylammonium bromide (BDDABr) have been developed. Optimum concentrations of PAN, Chromothrop 2B, BDDABr and pH ensuring maximum absorbance were defined. The effect of foreign ions was elucidated. The c...
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The study is a description of a sensitive spectrophotometric determination of aceclofenac following azo dye formation with 4-carboxyl-2,6-dinitrobenzenediazonium ion (CDNBD). Spot test and thin layer chromatography revealed the formation of a new compound distinct from CDNBD and aceclofenac. Optimization studies established a reaction time of 5 min at 30 degrees C after vortex mixing the drug/C...
متن کاملApplication of membrane filters for spectrophotometric determination of cationic surfactants in river water and sediment.
Cationic surfactant (CS+) in urban river water and sediment was extracted and determined spectrophotometrically with 2 membrane filters. The CS+ in the water samples, mostly in the form of an ion associate with the coexisting anionic surfactant (AS), was collected on a polytetrafluoroethylene (PTFE) membrane filter and eluted with methanol. Bromphenol blue (BPB), hydrochloric acid, and water we...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 2003
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.52.899